Cross sections of ZrB2-SiC oxidized in air for 10-min cycles show rapid attack.
Ultra-high-temperature ceramics (UHTC) are a group of materials consisting of zirconium diboride (ZrB2) or hafnium diboride (HfB2) plus silicon carbide (SiC), and in some instances, carbon (C). They offer a combination of properties that make them candidates for airframe leading edges on sharp-bodied reentry vehicles. These UHTCs perform well in the environment for such applications (i.e., air at low pressures). The purpose of this study at the NASA Glenn Research Center was to examine three of these materials under conditions more representative of a propulsion environment: that is, higher oxygen partial pressure and total pressure. Relatively long, multiple-exposure cycles were emphasized. We completed an in-house study of ZrB2 plus 20 vol% SiC (abbreviated as ZS), ZrB2 plus 14 vol% SiC and 30 vol% C (ZSC), and SCS-9a SiC fiber-reinforced ZrB2 plus 20 vol% SiC (ZSS). HfB2-based compositions were not included in the study because of their high cost.
The capability of UHTC for propulsion applications must be compared with that of mature, available, and commercially used ceramics such as silicon nitride (e.g., AS-800) to put things in proper perspective. In terms of mechanical properties, UHTCs fall short in terms of strength and fracture toughness. At about 1300 °C, the creep resistance of ZS appears to be superior to the creep resistance reported for AS-800. However, the stress rupture life for Si3N4 under stress and temperature conditions similar to those used in this study is measured in hundreds of hours. Because of oxidation, ZS could not achieve such lives.
In terms of oxidation resistance, acceptable amounts of material recession in 1 hour to thousands of hours, depending on the specific propulsion application, are on the order of 100 to 300 mm. This converts to an acceptable range of parabolic recession rate constants kp" of approximately less than or equal to 10-1 to 10-2 mm2/hr for a 1-hr application. For a 100-hr application, an acceptable range of kp" would be less than or equal to those values divided by 100. For the more oxidation resistant ZS material, measured parabolic recession rate constants were 4.7×10-3 mm2/hr at 1327 °C, 7.8×10-2 mm2/hr at 1627 °C, and 1.3 mm2/hr at 1927 °°C. Thus, recession rate constants for ZS are acceptable at 1327 °C for a 1-hr application, but here silicon nitride is a superior material. At 1627 °C, ZS oxidation is marginal for a 1-hr application, but dimensional growth would be an issue. In a 100-hr application, ZS cannot be considered at any temperature.
Our cursory examination of thermal shock, both from a theoretical and experimental viewpoint, indicated that the ZS and ZSC UHTCs are inferior to AS-800 silicon nitride. On the basis of this limited study, UHTCs are not ready to be considered as aeropropulsion materials for any applications longer than a few minutes. Current materials suffer from aggressive oxidation and moisture attack (Quynhgiao Nguyen, NASA Glenn, and Raymond C. Robinson, QSS Group, Inc., Cleveland, OH, 2002, private communication), and they are susceptible to thermal shock. For long-term propulsion applications, major improvements in environmental durability are needed. Work is in progress to improve the oxidation resistance of UHTC materials.
Find out more about this research:
Glenn’s Ceramics Branch
Glenn’s Environmental Durability Branch
Levine, Stanley, R., et al.: Evaluation of Ultra-High Temperature Ceramics for Aeropropulsion Use. J. Eur. Ceram. Soc., vol. 22, 2002, pp. 2757-2767.
Glenn contact: Dr. Stanley R. Levine, 216-433-3276, Stanley.R.Levine@nasa.gov
Cleveland State University contact: Dr. Elizabeth J. Opila, 216-433-8904, Elizabeth.J.Opila@nasa.gov
Authors: Dr. Stanley R. Levine, Dr. Elizabeth J. Opila, Michael C. Halbig, James D. Kiser, Dr. Mrityunjay Singh, and Dr. Jonathan A. Salem
Headquarters program office: OAT
Programs/Projects: Propulsion Systems R&T, UEET, STR
Last updated: June 25, 2003
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